Rationale for the sluggish oxidative addition of aryl halides to Au(i)
نویسندگان
چکیده
منابع مشابه
Mechanism of the oxidative addition of aryl halides to bis-carbene palladium(0) complexes*
Bis-N-heterocyclic carbenes Pd0 complexes, Pd(NHC)2, are efficient catalysts in Heck reactions performed with aryl bromides or chlorides. The Pd(NHC)2 that are not stable are generated in situ from PdII precursors PdY2(NHC)2 (Y = halides) after a chemical reduction. The latter procedure can be mimicked by an electrochemical reduction. The transient Pd(NHCBn)2 is generated by electrochemical red...
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ژورنال
عنوان ژورنال: Chem. Commun.
سال: 2014
ISSN: 1359-7345,1364-548X
DOI: 10.1039/c3cc48914k